There are two different sets, the TOURNAMENT set and the POKER set. Take a look at the chipguide (when you get a chance send in the scan of the 100 please). Pictured are the POKER for the 25 and 100 and then the TOURNAMENT for the rest. I remember them being intermixed at this point.

http://themogh.org/cg_chip_search.php?ccg=058737

I wouldn't value the 100 too high, maybe $10-15, they are fairly easy to get hold of. The 5000 usually come out later in the tournament or are of too high a value earlier for any of the harvesters out there. I would go higher on that one. Maybe up to $40-45 (although some would sell them higher).